I'll just post the series in which the events occur. Lots of recent stuff you missed. Potential spoilers.
Had sex with a skrull (Mighty Avengers)
Maria Hill (Invincible Iron Man)
Emma Frost (Civil War referenced)
She Hulk (She Hulk)
Echo (New Avengers)
> Scarlet Witch: Vision, and Wonder Man.
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Hawkeye (New Avengers)
Namora (Incredible Herc)
Snowbird (Incredible Herc)
BK did call Sersi his ex girlfriend in a recent Captain Britain issue.
Bucky/Cap (Captain America)
Abigail Brand, Director of Sword (Astonishing X-Men)
Implied Dazzler, they were in a relationship.
Ms. Marvel/Warbird (Ms. Marvel)
Wonderman (Ms. Marvel)
Had sex with a skrull posing as Pym (Avengers Initiative)
Skrull Queen which produced Hulking (Young Avengers)
Implied Ms. Marvel, with whom he had a relationship (Captain Marvel mini)
His current gf? They are engaged (Fantastic Four)
Nameless woman who had his son (Namor miniseries)
Emma Frost (Uncanny X-Men)
Nameless woman who had his son (Secret Warriors/Might Avengers)
Implied Shroud, with whom she had a relationship (Ms. Marvel)
Sentry (New Avengers)
Black Cat (Black Panther)
Where was Jessica Drew stated/implied?
Implied Wolverine
Crystal (New Avengers)
Lots of nameless/unimportant women.
Istu, mother of Daken (Wolverine: Origins)
Atsuko (Logan miniseries)
Silver Fox is pretty certain.
Yukio
Implied Jessica Drew, Elektra, She-Hulk, Black Widow
Thypoid Mary (Marvel Comics Presents)
Storm was never implied.
Neither Wolverine or Daredevil
Clint Barton/Hawkeye/Ronin (New Avengers)
Night Nurse (New Avengers)
> New Captain America/Bucky:
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Black Widow (Captain America)
Implied various girls during WWII.
Gwen Stacey (Amazing Spider-Man)
His wife
Implied Hawkeye/Clint Barton.
